Influence of lanthanum on enhancement of mechanical and electrical properties of Cu-Al_2O_3 composites

Two kinds of Cu-Al_2O_3 composites(with and without La) were prepared via mechanical alloying-spark plasma sintering(MA-SPS) method. Microstructure, mechanical properties and electrical resistivity were investigated systematically using metallography, scanning electron microscopy, transmission electron microscopy, mechanical and electrical properties testing. The results indicate that an appropriate amount of La can homogenize the distribution of Al_2O_3. As such, yield strength, ultimate tensile strength and elongation of Cu-Al_2O_3-La are greatly increased. Some semi-coherent interface between Cu and Al_2O_3 is found, which means a low interface energy. The grain shape of Cu changes to irregular band with the addition of La. This change results in a density decrease of grain boundary and reduces electrical resistance. Lanthanum may exist in the form of La_2O_3.     

卷取温度对超低碳T-3CA第二相析出的影响

 为研究卷取温度对超低碳T-3 CA中第二相粒子析出行为的影响，采用金相、TEM等检测手段，分析了580、630、680 ℃ 3个典型卷取温度下超低碳T 3 CA中第二相粒子的析出特性，结果发现卷取温度越高，热轧形成的TiC粒子尺寸越粗大，分布越稀疏。结合相关动力学计算分析了卷取温度对TiC粒子沉淀析出时临界晶核尺寸、相对形核率、相对沉淀析出时间的影响。结果表明，随着卷取温度由580提高到680 ℃，TiC粒子沉淀析出时临界晶核尺寸增大约1.0 nm，相对形核率降低约1.0个数量级，相对沉淀析出孕育时间增大约0.8个数量级。     

Electric transport properties of rare earth doped YbxCa1-xMnO3 ceramics (part I: Optimization of ceramic processing)

A comprehensive study was performed in order to find the effect of different calcination and sintering conditions on the physical properties of calcium manganite ceramics in dependence of temperature T and partial pressure of oxygen p(O₂). The eventual formation of oxygen vacancies during sintering was investigated and the results were confirmed by monitoring the release of oxygen using a ZrO₂ oxygen sensor. The phase transition behavior was studied using thermogravimetric analysis (TGA) in a wide range of p(O₂) ≈ 10^?1 MPa down to 10^-19 MPa at high temperatures accompanied by dilatometry- and XRD-measurements. Furthermore, the present study reveals for the first time a way for reducing and preventing crack formation that may occur during sintering. The present systematic research provides essential fundamental information before performing electrical measurements necessary in order to understand important factors about charge carriers and electrical transport mechanism.     

海洋非成岩天然气水合物原位快速制备实验及评价

我国的海洋天然气水合物（以下简称水合物）资源主要分布在沿海大陆架水深介于300～3 000 m的深水区，具有弱胶结、非成岩的特征，为了测试和研究该类型水合物必须原位、大量、快速制备样品，而目前常用的搅拌法、喷淋法、鼓泡法等制备技术却存在着生成速度慢、储气密度低等问题。为此，自主设计、研制了1 062 L非成岩水合物快速制备釜，针对我国南海非成岩水合物的物性特征，开展了搅拌法、鼓泡法、喷淋法单一制备方法及“三合一”法（上述3种方法相结合）水合物制备实验，测试了实验过程中温度、压力、电阻率及反应时间等数据，分析比较了几种不同制备方法的水合物生成情况与制备效率。实验结果表明：①搅拌法、鼓泡法、喷淋法制备水合物过程中，生成的水合物均缓慢增加并逐渐铺满整个液面；②搅拌法制备过程中可以观测到明显的诱导期，而喷淋法、鼓泡法及“三合一”法却无明显的诱导期；③单一制备方法及“三合一”法制备水合物过程中，电阻率均随反应时间的增加而增加，其变化趋势亦与水合物制备速率基本一致；④“三合一”法的制备周期明显短于单一制备方法（搅拌法、喷淋法、鼓泡法单一方法的制备时间分别约为“三合一”法的5.14倍、3.59倍、3.16倍）。结论认为，所研制的1 062 L水合物快速制备釜能够实现海洋非成岩水合物样品的原位、快速制备；较之于单一制备方法，“三合一”法大大提高了水合物的制备效率。     

超级电容器的电性能及其在智能仪表上的应用

超级电容器作为一种新型储能元件,目前应用越来越广泛,但在很多细分市场还处于培育阶段,相关行业标准也不尽完善。文中以超级电容器的等效电路模型引出了电性能的特征参数,对比分析了主要标准中电性能特征参数测试方法的差异,提出了在智能仪表中应用超级电容器的要点,对全面认识超级电容器的电性能,在实际工作中正确的应用超级电容器,有一定的参考价值。     

基于GF-1数据的三峡库区水体信息精细化提取

为实现江河类狭长型水体信息的精细化提取，利用GF-1卫星数据，采用支持向量机和目视解译相结合的方法对三峡库区及重庆市水体信息进行了精细化提取。使用总体分类精度、Kappa系数、错分误差、漏分误差、制图精度和用户精度等指标对库区水体信息粗提取结果进行验证分析。结果表明:4个试验区水体提取的总体分类精度均超过90%，除试验区4的Kappa系数为0.884 1以外，其余试验区均超过0.9，提取精度较高。结合目视解译的方法，在粗提取结果的基础上对各问题进行精细化处理，得到精度高、完整性好的三峡库区以及重庆市水体信息数据，可为后续该区域的精细化遥感业务开展提供有效资料。     

基于多特征融合的电影推荐系统

协同过滤算法（CF）根据用户-物品的评分矩阵做推荐，未考虑物品自身属性。本文将MovieLens数据集上的电影属性，作为影响推荐结果的因素，融合电影的简介、评论、评分、导演和演员等多种因素，进行推荐。使用CNN（卷积神经网络）和Word2Vec（Word to Vector,词向量模型）处理电影简介；使用AFINN（Finn rup Nielsen情感词典）处理评论，并对结果进行映射；对导演和演员数据进行建模，得到该因素下的预测评分，最后将各因素下的结果进行加权融合，通过调整权重，得到最佳效果。经验证，该方法的推荐性能优于传统的CF算法。     

Using discussion logic in analyzing online group discussions: A text mining approach

We propose a Discussion Logic-based Text Analytics (DiLTA) framework, which combines theories developed in social science and text mining fields. The framework extracts features that uncover discussion logic and uses these features in analyzing online discussions. A series of models are proposed including conversation disentanglement, coherence analysis, and visualization. Validation experiments showed that DiLTA achieved significantly superior performance over existing text analytics methods in reconstructing internal structure. A case study using DiLTA-enabled visualization on a healthcare forum illustrates the great potential of DiLTA in assisting comprehension of the internal linkage, structure, and logic of online group discussions.     

Development of a void ratio-moisture ratio-net stress framework for the prediction of the volumetric behavior of unsaturated granular materials

Despite extensive research on the behavior of unsaturated fine-grained materials, there is still a lack of understanding of the volumetric behavior of unsaturated granular materials. In this research, a model has been developed to predict the fundamental volumetric behavior of unsaturated granular materials through loading and wetting state paths. In this regard, a loading-wetting surface was developed in a space of void ratio-moisture ratio-net stress. A distinctive feature of the proposed model is the relative simplicity in obtaining the model parameters using conventional geotechnical testing equipment. Two types of recycled granular materials, commonly applied in unbound pavements were used, namely, recycled crushed brick (CB) and excavation waste rock (WR). The uniqueness of the developed surface was evaluated by employing a number of loading and wetting state paths. The results indicate that the developed surface is unique in its loading state paths; however, it only shows uniqueness in its wetting state paths for stress levels greater than 2000 kPa. The proposed model seeks to introduce the application of the unsaturated soil mechanics theory, for predicting the behavior of granular materials in the field, by providing a practical and cost-effective methodology.     

Synthesis and Application of Methyl N,O-Hydroxylamine Muramyl Peptides

The innate immune system's interaction with bacterial cells plays a pivotal role in a variety of human diseases. Carbohydrate units derived from a component of bacterial cell wall, peptidoglycan (PG), are known to stimulate an immune response. Nonetheless, access to modified late-stage peptidoglycan intermediates is limited due to their synthetic complexity. A method to rapidly functionalize PG fragments is needed to better understand the natural host–PG interactions. Here methyl N,O-hydroxylamine linkers are incorporated onto a synthetic PG derivative, muramyl dipeptide (MDP). The modification of MDP maintained the ability to stimulate a nuclear factor kappa-light-chain-enhancer of activated B cells (NF-κB) immune response dependent on the expression of nucleotide-binding oligomerization domain-containing protein 2 (Nod2). Intrigued by this modification's maintenance of biological activity, several applications were explored. Methyl N,O-hydroxylamine MDP was amendable to N-hydroxylsuccinimide (NHS) chemistry for bioconjugation to fluorophores as well as a self-assembled monolayer for Nod2 surface plasmon resonance analysis. Finally, linker incorporation was applicable to larger PG fragments, both enzymatically generated from Escherichia coli or chemically synthesized. This methodology provides rapid access to PG probes in one step and allows for the installation of a variety of chemical handles to advance the molecular understanding of PG and the innate immune system.